T. Kaneko, S. Tanaka, N. Asao, Y. Yamamoto,M.W.Chen, W. Zhang, and A. Inoue, Stabilizer and Ligand-Free Catalyst, Adv. Synth. Catal. 353 -2011 2927-2932.

Abstract

Nanoporous metallic glass palladium (PdNPore), which was fabricated by de-alloying of a glassy metallic alloy Pd30Ni50P20, exhibited a remarkable catalytic activity for the Heck reaction of versatile aryl iodides and aryl bromides. Moreover, the PdNPore can be reused several times without a significant loss of catalytic activity, and the PdNPore has ahigher resistance to leaching than palladium black and palladium on carbon.

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